Each execution profile has an associated profile, a command that it applies to, and a set of user and group rights that the command is run with. These additional rights will only be used if the command is run from a profile-aware shell, such as pfcsh or pfsh.
If you have created your own profiles, you can use this page to add commands to run to them. However, execution profiles that are included as standard with the operating system should not be modified unless you know what you are doing.